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The first references to hydrogen fuel cells appeared in 1838. In a letter dated October 1838 but published in the December 1838 edition of The London and Edinburgh Philosophical Magazine and Journal of Science, Welsh physicist and barrister William Grove wrote about the development of his first crude fuel cells. He used a combination of sheet iron, copper and porcelain plates, and a solution of sulphate of copper and dilute acid.[4][5] In a letter to the same publication written in December 1838 but published in June 1839, German physicist Christian Friedrich Schnbein discussed the first crude fuel cell that he had invented.

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