The maximum coordination number for a certain metal is thus

The s, p, and d orbitals of the metal can accommodate 18 electrons (see 18 Electron rule). The maximum coordination number for a certain metal is thus related to the electronic configuration of the metal ion (to be more specific, the number of empty orbitals) and to the ratio of the size of the ligands and the metal ion. [Mo(CN)8]4.

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